Simulation of capacity loss in carbon electrode for lithium-ion cells during storage

A mathematical model was developed which simulates the self-discharge capacity losses in the carbon anode for a SONY 18650 lithium-ion attery. The model determines the capacity loss during storage on the basis of a continuous reduction of organic solvent and de-intercalation of ithium at the carbon/electrolyte interface. The state of charge, open circuit potential, capacity loss and film resistance on the carbon electrode were alculated as a function of storage time using different values of rate constant governing the solvent reduction reaction. 2007 Elsevier B.V. All rights reserved.